Vassiliki Papadimitriou is a graduate of the Department of Library Science and Information Systems of the Technological Educational Institute of Athens. She started off her professional career in 2005 as an intern in the Library of the School of Physical Education and Sports Science of the National and Kapodistrian University of Athens. Then, she worked in the Library of the Hellenic Parliament from 2006 to 2008, in the research programs entitled "Reorganisation and modernisation of the Library of the Hellenic Parliament","Retrospective cataloguing of the Library of the Hellenic Parliament", "Documentation, development and promotion of the collections of the Library of the Hellenic Parliament". After that, she was employed in the Academy of Theological Studies of Volos, as well as in the Historical Archives of the Holy Metropolis of Demetrias between the years 2014 and 2016. She has been working as a librarian in the Academy of Theological Studies of Volos since 2017.